Refactor FindMostWorkChain

Summary: Chaneg the flow a bit to reduce nesting, and add a few comments.

Test Plan:

make check
./test/functional/test_runner.py

Reviewers: #bitcoin_abc, jasonbcox

Reviewed By: #bitcoin_abc, jasonbcox

Subscribers: jasonbcox, teamcity

Differential Revision: https://reviews.bitcoinabc.org/D1945